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Crystal structure of di-μ-chlorido-bis-[di-chlorido(l-histidinium-κ)cadmium(II)].

Acta Crystallogr E Crystallogr Commun. 2019-06; 
MohamediNacira,ElleuchSlim,BoufasSihem,LegouiraMessaoud,DjaziFai
Products/Services Used Details Operation
Codon Optimization … 82 % N N Br 50 % over 2 steps O OEt O O Page 6. S6 3. Molecular Biology Gene optimization: The synthesized gene of LmrR was ordered from GenScript (USA). The codon usage was adapted to the codon bias of E. coli genes. The gene was delivered in the cloning vector … Get A Quote

摘要

In the title compound, [Cd(CHNO)Cl], the coordination polyhedra around the Cd cations are distorted trigonal bipyramids. Two of the chloride ions (one axial and one equatorial) are bridging to the other metal atom, leading to a Cd⋯Cd separation of 3.9162 (4) Å. The O atom of the l-histidinium cation lies in an axial site. In the crystal, numerous N-H⋯Cl, N-H⋯O, C-H⋯O and C-H⋯Cl hydrogen bonds link the mol-ecules into a three-dimensional network. Theoretical calculations and spectroscopic data are available as supporting information.

关键词

X-ray diffraction,crystal structure,dinuclear cadmium compounds,electronic properties,hybrid materials,hydrogen b